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By the time it would have reached his room to wake him up, he probably would have been unconscious from smoke inhalation.
I think sprinklers would be a better idea too.
When I was sharing a flat years ago we lived in the flat for 3 years and when we came to move out we gave the whole place a cleanout first, we found a shrunken green chicken in the oven. Neither of us had ever used the oven in the whole time we were there so it must have been from the tenants before us. One of the downsides of having a takeaway shop over the road I guess :-)
Also, I first read "to wake up the dead" ... that kinda confused me.
Anyways, I think there`d be an application for this in alarm clocks. It`d be extreme but some people, like myself, need an extreme alarm clock.
But still! Cool.
The horseradish/wasabi smell would be effective, I think...
Oh, and not all people wake up with sprinklers on their faces...
and wouldnt the smell of smoke wake you up with the same results of the wasabi?